No, it will not work with PicoScope 6 Automotive, PicoDiagnostics, or provide access to the waveform library.
The maximum input voltage range is only +/-20V , the Automotive Scopes are +/-200V and have better input protection, and the vertical resolution is only 8 bit compared to the 12 bit on the automotive scope so you will see less detail.
It may not be the best purchase even if competitively priced.